When referring to the Spectral Atlas, please cite our publication:
Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen,
R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of
atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013),
DOI: 10.5194/essd-5-365-2013
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DATAFILE: | ClOOCl(not,ratherCl2O3)_MolinaMolina(1987)_240K_200-346nm.txt |
NAME: | dichlorine dioxide or dichlorine trioxide |
FORMULA: | ClOOCl(not,ratherCl2O3) |
AUTHOR(YEAR): | MolinaMolina(1987) |
T: | 240K |
λ: | 200-346nm |
BIBLIOGRAPHY: |
L.T. Molina and M.J. Molina, "Production of Cl2O2 from the self-reaction of the ClO radical",
J. Phys. Chem. 91, 433-436 (1987);
DOI: 10.1021/j100286a035
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COMMENTS: | Reaction of Cl atoms with one of three different ClO precursors: O3, Cl2O, or OClO and absorption measurements using a double beam spectrophotometer
The spectrum has been assigned to ClOOCl, but later identified as Cl2O3, see e.g. M.H. Harwood, D.M. Rowley, R.A. Freshwater, R.A. Cox, and R.L. Jones, "A spectroscopic study of Cl2O3," J. Chem. Soc. Faraday Trans. 91, 3027-3032 (1995); DOI: 10.1039/FT9959103027 |
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